I just got an account open on Tuesday and I'm still new at it. I need money to buy some school books before Monday and my card isn't suppose to arrive until Tuesday. It's from Bank of America.. so does anyone know?

Well, assuming that temporary debit card is from the same company and is assigned to the same bank account, then sure. I mean, the reason why they gave you a "temporary" debit card was so that you can use it until your new one arrives, right?